Biomass-derived carbon from Ganoderma lucidum spore as a promising anode material for rapid potassium-ion storage

被引:85
作者
Yang, Mengmeng [1 ]
Dai, Jinyan [1 ]
He, Minyi [1 ]
Duan, Tao [1 ]
Yao, Weitang [1 ]
机构
[1] Southwest Univ Sci & Technol, Fundamental Sci Nucl Wastes & Environm Safety Lab, 59 Qinglong Ave, Mianyang 621010, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
Biomass-derived carbon; Ganoderma lucidum spore; Potassium ion battery; Anodes; POROUS CARBON; DOPED CARBON; RATE CAPABILITY; COMPOSITE; BATTERIES; NANOTUBES; MECHANISM; LIFE;
D O I
10.1016/j.jcis.2020.02.023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The design and preparation of powerful anode materials are key to developing potassium-ion batteries. A biomass-based potassium anode material with a distinct hollow-cage structure was prepared by one-step carbonization. The target carbon exhibited a specific surface area of 104.4 m(2) g(-1), and mesopores/macropores distributed materials. When used as the negative electrode of a potassium-ion battery, the cagelike porous carbon (CPC) showed a reversible capacity of 407 mAh g(-1), after 50 cycles at 50 mA g(-1), current density. After 100 cycles, at a current density of 200 mA g(-1), the reversible capacity was 163.8 mAh g(-1). It still exhibits an extremely long cycle stability at high current densities (discharge capacity of 124.6 mAh g(-1) after 700 cycles at a current density of 1 A g(-1)). The excellent performance is attributed to the stable cage-like carbon scaffold and uniform continuous distribution of mesopores/macropores to improve ion diffusion kinetics and electronic conductivity. These results indicate that a properly designed CPC can effectively increase the capacity and cycle stability of a potassium-ion battery. (C) 2020 Elsevier Inc. All rights reserved.
引用
收藏
页码:256 / 263
页数:8
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