An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

被引：3

作者：

Bookham, JL ^{[1
]}

机构：

[1] Northumbria Univ, Dept Chem & Life Sci, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 08期

关键词：

inversion; tungsten complexes; carbonyl complexes; diphosphine complexes;

D O I：

10.1016/S1387-7003(98)00083-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Quantitative inversion at the chiral sp(3) hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C-2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar = 2-pyridyl) occurs at moderately elevated temperatures. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：309 / 313

页数：5

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