Synthesis of Cu2O from CuO thin films: Optical and electrical properties

被引:185
|
作者
Murali, Dhanya S. [1 ]
Kumar, Shailendra [2 ]
Choudhary, R. J. [3 ]
Wadikar, Avinash D. [3 ]
Jain, Mahaveer K. [1 ]
Subrahmanyam, A. [1 ]
机构
[1] Indian Inst Technol, Dept Phys, Madras 600036, Tamil Nadu, India
[2] RR Ctr Adv Technol, Indus Synchrotrons Utilizat Div, Indore 452013, Madhya Pradesh, India
[3] UGC DAE Consortium Sci Res, Indore 452001, Madhya Pradesh, India
来源
AIP ADVANCES | 2015年 / 5卷 / 04期
关键词
COPPER-OXIDE SEMICONDUCTORS;
D O I
10.1063/1.4919323
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Hole conducting, optically transparent Cu2O thin films on glass substrates have been synthesized by vacuum annealing (5x10(-6) mbar at 700 K for 1 hour) of magnetron sputtered (at 300 K) CuO thin films. The Cu2O thin films are p-type and show enhanced properties: grain size (54.7 nm), optical transmission 72% (at 600 nm) and Hall mobility 51 cm(2)/Vs. The bulk and surface Valence band spectra of Cu2O and CuO thin films are studied by temperature dependent Hall effect and Ultra violet photo electron Spectroscopy (UPS). CuO thin films show a significant band bending downwards (due to higher hole concentration) than Cu2O thin films. (C) 2015 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.
引用
收藏
页数:5
相关论文
共 17 条
  • [1] Tailoring of electrical properties of Cu2O thin films fabricated by oxygen injection after argon plasma reduction of CuO films
    Badillo-Avila, M. A.
    Castanedo-Perez, R.
    Marquez-Marin, J.
    Torres-Delgado, G.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (07) : 5674 - 5685
  • [2] Thermal conversion of Cu4O3 into CuO and Cu2O and the electrical properties of magnetron sputtered Cu4O3 thin films
    Murali, Dhanya S.
    Aryasomayajula, Subrahmanyam
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2018, 124 (03):
  • [3] Luminescence Properties of Epitaxial Cu2O Thin Films Electrodeposited on Metallic Substrates and Cu2O Single Crystals
    Trinkler, Laima
    Dai, Dajin
    Chang, Liuwen
    Chou, Mitch Ming-Chi
    Wu, Tzu-Ying
    Gabrusenoks, Jevgenijs
    Nilova, Dace
    Ruska, Rihards
    Berzina, Baiba
    Nedzinskas, Ramunas
    MATERIALS, 2023, 16 (12)
  • [4] Selective spatial atomic layer deposition of Cu, Cu2O, and CuO thin films in the open air: reality or fiction?
    Sekkat, A.
    Weber, M.
    Lopez-Sanchez, J.
    Rabat, H.
    Hong, D.
    Rubio-Zuazo, J.
    Bellet, D.
    Chichignoud, G.
    Kaminski-Cachopo, A.
    Munoz-Rojas, D.
    MATERIALS TODAY CHEMISTRY, 2023, 29
  • [5] Single-phase Cu2O and CuO thin films obtained by low-temperature oxidation processes
    Guillen, C.
    Herrero, J.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 737 : 718 - 724
  • [6] First-Principles Study on the Structural and Magnetic Properties of Low-Index Cu2O and CuO Surfaces
    Bogenrieder, Stefanie E.
    Bessner, Julian
    Engstfeld, Albert K.
    Jacob, Timo
    JOURNAL OF PHYSICAL CHEMISTRY C, 2024, 128 (23) : 9693 - 9704
  • [7] Morphological and stoichiometric optimization of Cu2O thin films by deposition conditions and post-growth annealing
    Umar, Medina
    Swinkels, Milo Y.
    De Luca, Marta
    Fasolato, Claudia
    Moser, Lucas
    Gadea, Gerard
    Marot, Laurent
    Glatzel, Thilo
    Zardo, Ilaria
    THIN SOLID FILMS, 2021, 732 (732)
  • [8] Electrodeposition of Cu2O nanostructures with improved semiconductor properties
    Boulett, Andres
    Pizarro, Guadalupe Del C.
    Martin-Trasanco, Rudy
    Sanchez, Julio
    Tasca, Federico
    Linarez Perez, Omar E.
    Tello, Alejandra
    Oyarzun, Diego P.
    COGENT ENGINEERING, 2021, 8 (01):
  • [9] Ni dependent structural, optical and electrical properties of CuO nanostructures
    Kuanr, Sushil Kumar
    Nayak, Shovan
    Babu, K. Suresh
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2017, 71 : 268 - 274
  • [10] Synthesis of low resistive p type Cu4O3 thin films by DC reactive magnetron sputtering and conversion of Cu4O3 into CuO by laser irradiation
    Murali, Dhanya S.
    Subrahmanyam, A.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2016, 49 (37)