catena-Poly[[[dipyridinecopper(II)]-μ-2,3,5,6-tetramethylbenzene-1,4-dicarboxylato] monohydrate]

被引:0
作者
Hu, Xiaoqin [1 ]
机构
[1] N Univ China, Dept Chem, Taiyuan 030051, Shanxi, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S1600536810036913
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, {[Cu(C(12)H(12)O(4))(C(5)H(5)N)(2)]center dot H(2)O}(n), the Cu(II) ion lies on an inversion center and is coordinated by two O atoms from two 2,3,5,6-tetramethylbenzene-1,4-dicarboxylate (TBDC) ligands and two N atoms from two pyridine ligands in a slightly distorted square-planar environment. The TBDC ligands act as bridging ligands, forming chains along [110]. These chains are further linked into a two-dimensional network via intermolecular O-H center dot center dot center dot O hydrogen bonds. The solvent water molecule lies on a twofold rotation axis.
引用
收藏
页码:M1301 / U1216
页数:10
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