Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-Spiroxin C

被引：39

作者：

Ando, Yoshio ^{[1
]}

Hanaki, Atsuko ^{[1
]}

Sasaki, Ryota ^{[1
]}

Ohmori, Ken ^{[1
]}

Suzuki, Keisuke ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528551, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 38期

关键词：

naphthoquinones; photochemistry; redox reactions; stereospecificity; total synthesis; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; ASYMMETRIC TRANSFER HYDROGENATION; KETONES; CHIRALITY; MEMORY; DEHYDROGENATION; CONVERSION; SPIROXINS; ALDEHYDES; ALCOHOLS;

D O I：

10.1002/anie.201705562

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (-)-spiroxin C.

引用

页码：11460 / 11465

页数：6

共 39 条

[1] Intramolecular Photoredox Reaction of Naphthoquinone Derivatives (vol 28, pg 1040, 2017) [J].