Synthesis and preliminary studies on a novel class of soluble amino alcohol reagents based on methacrylate copolymers

被引：5
作者：
Edwards, CW
Haddleton, DM
Morsley, D
Shipton, MR
Wills, M
机构：
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[2] GlaxoSmithKline Pharmaceut PLC, Med Res Ctr, Stevenage SG1 2NY, Herts, England
来源：
TETRAHEDRON | 2003年 / 59卷 / 31期
关键词：
soluble polymers; asymmetric; catalyst; ligand; dialkylzinc;
D O I：
10.1016/S0040-4020(03)00975-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A class of soluble polymers containing chiral beta-amino alcohol ligands, based on methacryate copolymers, are described. The use of copolymers permits the selective introduction of material to control the solubility and a functional group in a controllable ratio and polymer length. The application of the supported polymers to diethylzinc additions is described. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5823 / 5830
页数：8
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