Rhodium(III)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates

被引：78
|
作者：
Feng, Chao [1 ]
Feng, Daming [1 ]
Loh, Teck-Peng [1 ,2 ]
机构：
[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 02期
关键词：
CROSS-COUPLING REACTION; CATALYZED OLEFINIC TRIFLUOROMETHYLATION; OXIDATIVE HECK REACTIONS; ENANTIOSELECTIVE SUBSTITUTION; ARYLBORONIC ACIDS; ARYL IODIDES; OLEFINATION; ACRYLATES; ENAMIDES; ARENES;
D O I：
10.1039/c4cc07597h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent gamma-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.
引用
收藏
页码：342 / 345
页数：4
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