The reduction of wustite with high oxygen enrichment and high injection of hydrogenous fuel

被引:30
作者
Li, Jiaxin [1 ]
Wang, Ping [1 ]
Zhou, Liying [1 ]
Cheng, Miao [1 ]
机构
[1] Anhui Univ Technol, Sch Met & Resources, Anhui 243002, Maanshan, Peoples R China
关键词
blast furnace; reduction of wustite; oxygen enrichment; hydrogen; water-gas shift reaction;
D O I
10.2355/isijinternational.47.1097
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
In order to reduce CO2 emission and energy consumption in a blast furnace, it is necessary to investigate the effects of some factors on direct reduction from wustite (FeO) to iron(Fe) with high oxygen enrichment and high injection of hydrogenous fuel, such as the composition and temperature of reducing gas mixture and the water-gas shift reaction. The current experiments reveal: (1) Reducing power of gas mixture with low oxygen enrichment and high PCI injection is limited, the reduction degree of wustite is 53.6% after 90 min at 1 000 degrees C; While with high oxygen in blast (40 %) and high natural gas injection (about 15 % H-2 in hearth gas), the reduction degree reaches 100 % after 64.81 min. In the case of reduction with pure oxygen and higher hydrogen, the reduction speed promotes further. At 900 degrees C, 100% reduction needs 64 min. (2) The utilization efficiency of hydrogen drops when H2 content is over 50% in the gas mixture without N-2. The optimum value of H2 content for pure oxygen blast furnace is between 15-30 % from the point of view of wustite reduction. (3) The water-gas shift reaction counteracts wustite reduction in the case of gas mixture with high content of CO2 and H-2 at elevated temperature.
引用
收藏
页码:1097 / 1101
页数:5
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