Optical studies of Sm3+ doped oxyfluoroborate glass

被引:104
作者
Mahato, KK [1 ]
Rai, DK [1 ]
Rai, SB [1 ]
机构
[1] Banaras Hindu Univ, Dept Phys, Laser & Spect Lab, Varanasi 221005, Uttar Pradesh, India
关键词
disordered systems; optical properties; luminescence;
D O I
10.1016/S0038-1098(98)00442-6
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Rare earth ion doped oxyfluoroborate glasses have been prepared with different concentration of Sm3+. The UV-Vis-NIR optical absorption, laser induced fluorescence and photoacoustic spectra of Sm3+ in this lattice have been studied. Optical parameters such as oscillator strength, stimulated emission cross-section, transition probability, radiative lifetime etc. have been calculated. Lifetime of the (4)G(5/2) level at various concentrations of Sm3+ have been used to explain the concentration dependent fluorescence quenching. The mechanism of quenching was found to involve quadrupole-quadrupole coupling. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:671 / 676
页数:6
相关论文
共 25 条
[1]   OPTICAL-TRANSITIONS OF DY-3+ IONS IN FLUOROZIRCONATE GLASS [J].
ADAM, JL ;
DOCQ, AD ;
LUCAS, J .
JOURNAL OF SOLID STATE CHEMISTRY, 1988, 75 (02) :403-412
[2]  
AVANESOV AG, 1983, SOV PHYS JETP, V57, P351
[3]   CALCULATION OF CRYSTAL-FIELD SPLITTING OF SM3+ AND DY3+ LEVELS IN LACL3 WITH INCLUSION OF J MIXING [J].
AXE, JD ;
DIEKE, GH .
JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (10) :2364-&
[4]   OPTICAL-TRANSITIONS OF SM3+ IN OXIDE GLASSES [J].
BOEHM, L ;
REISFELD, R ;
SPECTOR, N .
JOURNAL OF SOLID STATE CHEMISTRY, 1979, 28 (01) :75-78
[5]  
CANALEJO M, 1988, PHYS CHEM GLASSES, V29, P187
[6]   NEAR INFRARED TRANSITIONS OF TRIVALENT LANTHANIDES IN SOLUTION .1. PRASEODYMIUM(III), NEODYMIUM(III), SAMARIUM(III), AND EUROPIUM(III) IONS [J].
CARNALL, WT ;
MCBETH, RL ;
GRUEN, DM .
JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (11) :2159-&
[7]   SPLITTING OF THE NEAR-INFRARED ABSORPTION-BANDS OF SM3+ IN POCL3-SNCL4, POCL3-ZRCL4 AND POCL3-TICL4 [J].
CHRYSOCHOOS, J ;
TOKOUSBALIDES, P .
JOURNAL OF LUMINESCENCE, 1979, 20 (04) :359-371
[8]  
Dieke G.H., 1968, Spectra and Energy Levels of Rare Earth ions in Crystals
[9]  
FREIDRICK A, 1960, Z PHYS, V158, P251
[10]   ABSORPTION AND FLUORESCENCE PROPERTIES OF EU-3+ DOPED ALKALI MIXED HEAVY-METAL FLUORIDE GLASSES [J].
HARINATH, R ;
BUDDHUDU, S ;
BRYANT, FJ ;
XI, L .
SOLID STATE COMMUNICATIONS, 1990, 74 (10) :1147-1152