Statistical modeling and interpretation of Sono-assisted adsorption mechanism of Crystal Violet dye on FeTiPbO Nanocomposite

被引:10
作者
Jethave, Ganesh [1 ]
Attarde, Sanjay [1 ]
Fegade, Umesh [2 ]
Inamuddin [3 ]
Altalhi, Tariq [4 ]
Kanchi, Suvardhan [5 ,6 ]
Ingle, Sopan [1 ]
Dhake, Rajesh [7 ]
机构
[1] Kavayitri Bahinabai Chaudhari North Maharashtra U, Sch Environm & Earth Sci, Jalgaon, MS, India
[2] Bhusawal Arts Sci & PO Nahata Commerce Coll, Dept Chem, Bhusawal, MS, India
[3] Aligarh Muslim Univ, Zakir Husain Coll Engn & Technol, Fac Engn & Technol, Adv Funct Mat Lab,Dept Appl Chem, Aligarh 202002, Uttar Pradesh, India
[4] Taif Univ, Dept Chem, Collage Sci, POB 11099, At Taif 21944, Saudi Arabia
[5] Durban Univ Technol, Dept Chem, ZA-4000 Durban, South Africa
[6] Sambhram Inst Technol, Dept Chem, Bengaluru 560097, India
[7] DDN Bhole Coll, Dept Chem, Jalgaon 425201, MH, India
关键词
Statistical analysis; Grand canonical ensemble; Double layer model; Density of receptor site; Energetic interpretation; ACTIVATED CARBON; AQUEOUS-SOLUTION; CONGO RED; MAGNETIC NANOPARTICLES; GREEN SYNTHESIS; METHYLENE-BLUE; WATER-VAPOR; REMOVAL; ISOTHERMS; OXIDE;
D O I
10.1016/j.molliq.2021.116878
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, Crystal Violet (CV) adsorption isotherm on FeTiPbONC was simulated and interpreted using the conventional methods as well as statistical physics two energies double layer model. This model was formalized based on the statistical physics. The following parameters are added in this pattern: steric and energy-sensitive parameters relevant to the adsorption mechanism. The findings of the mathematical model at temperatures 298, 308 , and 318 K givethe values of receptor site density (Nm) as 355.85, 50.91 and 26.815 mg/g, which reveals that maximum adsorption was achieved at lower temperature. The adsorption energies epsilon(1) (from 16.95 to 30.39 kJ/mol) and epsilon(2) (from 7.98 to 13.02 kJ/mol) increases as temperature rises, showing that the CV-FeTiPbONC contact is stronger than the CV-CV interaction. The results showed that FeTiPbONC might be employed as a nanoadsorbent for the removal of organic contaminants from an aqueous matrix. (C) 2021 Elsevier B.V. All rights reserved.
引用
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页数:10
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