Catalytic properties of RhSe2/Ga/H-ZSM-5 system in the reaction of glycerol dehydration in the gas phase

被引：5

作者：

Volkov, S. V. ^{[1
]}

Khar'kova, L. B. ^{[1
]}

Baranets, S. A. ^{[1
]}

Yanko, O. G. ^{[1
]}

Strizhak, P. E. ^{[2
]}

Kosmambetova, G. R. ^{[2
]}

Gritsenko, V. I. ^{[2
]}

机构：

[1] Natl Acad Sci Ukraine, Vernadsky Inst Gen & Inorgan Chem, Pr Akad Palladina 32-34, UA-03142 Kiev, Ukraine

[2] Natl Acad Sci Ukraine, Pisarzhevskii Inst Phys Chem, Pr Nauki 31, UA-03028 Kiev, Ukraine

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2016年 / 89卷 / 02期

关键词：

METHANE OXIDATIVE CARBONYLATION; RHODIUM CHALCOGEN HALIDES; SUPPORTS; ACROLEIN;

D O I：

10.1134/S1070427216020117

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Catalytic properties of the RhSe2/Ga/H-ZSM-5 system formed upon thermal treatment of a mechanical mixture of rhodium selenochloride Rh2Se9Cl6 and a gallium-containing zeolite Ga/H-ZSM-5 at 300-340A degrees C in a flow of nitrogen were studied in the course of glycerol dehydration in the gas phase. It was shown that the promotion of Ga/H-ZSM-5 with rhodium selenide RhSe2 makes higher the yield of the target product acrolein.

引用

页码：233 / 237

页数：5

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