Synthesis and ion-binding studies of a platinum(II) terpyridine complex with crown ether pendant.: X-ray crystal structure of [Pt(trpy)(S-benzo-15-crown-5)]PF6

被引：75

作者：

Yam, VWW ^{[1
]}

Tang, RPL ^{[1
]}

Wong, KMC ^{[1
]}

Ko, CC ^{[1
]}

Cheung, KK ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 03期

关键词：

D O I：

10.1021/ic000586q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A platinum(II) terpyridine complex containing the mercaptobenzo-15-crown-5 ligand, [Pt(trpy)(S-benzo-15-crown-5)]PF6, has been synthesized and characterized. Its cation binding properties are studied by UV-vis and further confirmed by ESI-MS. The structure has also been determined by X-ray crystallography.

引用

页码：571 / +

页数：5

共 46 条

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[22] FORMATION AND X-RAY CRYSTAL-STRUCTURE OF [PT(H2NCH2CH2NH2)2.18-CROWN-6]N2+[PF6]2N- - A HYDROGEN-BONDED STEPPED-CHAIN CO-POLYMER
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[26] SYNTHESIS OF SOME TETRAHEDRAL MIXED-METAL PLATINUM GOLD CLUSTERS AND THE X-RAY CRYSTAL-STRUCTURE OF [(AU(PCY3)()PT3(MU-CNXYL)2(MU-CO)(CNXYL)(PCY3)2)][PF6]
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[27] Preparation and X-ray crystal structure of a unique 2:1-complex of mercury(II) chloride and 5-oxa-2,8-dithia-bicyclo[7.4.1]tetradeca-9,11,13-trien-14-one, a troponoid dithio-crown ether
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