Silver-Catalyzed Synthesis of Enones/α-Iodoenones from Tertiary Propargyl Alcohols

被引：5
|
作者：
Naveen, Naganaboina [1 ]
Ramesh, Golla [1 ]
Balamurugan, Rengarajan [1 ]
机构：
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, India
来源：
CHEMISTRYSELECT | 2019年 / 4卷 / 46期
关键词：
Meyer-Schuster rearrangement; Tertiary propargyl alcohols; alpha; beta-unsaturated enones; alpha-iodoenones; AgSbF6; MEYER-SCHUSTER REARRANGEMENT; ALPHA; BETA-UNSATURATED ALDEHYDES; REDOX ISOMERIZATION; CASCADE SYNTHESIS; ALPHA-HALOENONES; GOLD; COMPLEX; KETONES; CYCLIZATION; METAL;
D O I：
10.1002/slct.201903568
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tertiary propargyl alcohols undergo smooth Meyer-Schuster rearrangement to give enones in the presence of silver catalyst alone at room temperature. The intermediate can be trapped using NIS to make useful tetra substituted alpha-iodoenones.
引用
收藏
页码：13610 / 13614
页数：5
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