Encapsulation of the uranyl dication

被引：36

作者：

Beer, Stephan ^{[1
]}

Berryman, Orion B. ^{[1
]}

Ajami, Dariush ^{[1
]}

Rebek, Julius, Jr. ^{[1
]}

机构：

[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

来源：

CHEMICAL SCIENCE | 2010年 / 1卷 / 01期

关键词：

STEREOGNOSTIC COORDINATION CHEMISTRY; PROCESS PHOSPHORIC-ACID; HYDROGEN-BONDS; PROTEIN-STRUCTURE; MOLECULES; COMPLEXES; ION; RECOGNITION; CATALYSIS; LIGANDS;

D O I：

10.1039/c0sc00116c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report here the application of self-assembly to the sequestration of uranyl ion, the dominant form of uranium on Earth. The assembly presents the ion with convergent carboxylate ligands, isolates it from solvent, encapsulates it with aromatic panels and allows its extraction from aqueous solutions in the presence of excess brine.

引用

页码：43 / 47

页数：5

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