Reactions of (RP)- and (SP)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with heteroatom nucleophiles;: preparation of P-chiral binol phosphinates and related compounds

被引：50

作者：

Au-Yeung, TL ^{[1
]}

Chan, KY ^{[1
]}

Chan, WK ^{[1
]}

Haynes, RK ^{[1
]}

Williams, ID ^{[1
]}

Yeung, LL ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(00)01950-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of (R-P)- and (S-P)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with metallated phenol and BINOL alkoxides, thioalkoxides, amides and enolates leading with clean inversion at phosphorus to phosphinates, phosphinothiolates and phosphinoamidates, and the corresponding thionophosphorus compounds are described. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：453 / 456

页数：4

共 11 条

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