Calcium-mediated intramolecular hydroamination catalysis

被引：341

作者：

Crimmin, MR ^{[1
]}

Casely, IJ ^{[1
]}

Hill, MS ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 07期

关键词：

D O I：

10.1021/ja043576n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The calcium-catalyzed intramolecular hydroamination of alkenes and alkynes is reported. The β-diketiminato complex [{HC(C(Me)2N-2,6-iPr2C6H3)2}-Ca{N(SiMe3)2}(THF)] affects catalytic cyclization of a range of aminoalkenes and aminoalkynes with activities that are broadly commensurate to those of established rare earth catalysts. Copyright © 2005 American Chemical Society.

引用

页码：2042 / 2043

页数：2

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