The structure and photoluminescence of Bi4Ti3O12 nanoplates synthesized by hydrothermal method

被引:33
作者
Gu, Haoshuang [1 ]
Hu, Zhenglong [1 ,2 ]
Hu, Yongming [1 ]
Yuan, Ying [1 ]
You, Jin [1 ]
Zou, Weidong [2 ]
机构
[1] Hubei Univ, Fac Phys & Elect Technol, State Key Lab Ferro & Piezoelect Mat & Devices Hu, Wuhan 430062, Peoples R China
[2] Xianning Coll, Dept Informat Engn, Xianning 437005, Peoples R China
基金
中国国家自然科学基金;
关键词
Bi4Ti3O12; nanoplates; photoluminescence;
D O I
10.1016/j.colsurfa.2007.08.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bismuth titanate (Bi4Ti3O12) nanoplates were synthesized by polyethylene glycol-assisted hydrothermal method at 200 degrees C. The as-prepared samples were investigated by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy and the room-temperature photolummescence. The Bi4Ti3O12 nanoplates are single crystalline and orthorhombic perovskite structure with the average rim sizes of about 200 nm and thickness of 10-20 nm. One blue-green photoluminescence band centered at around 470.4 nm was observed at room temperature. The investigation of the effects of the annealing temperatures on room-temperature visible emission showed that the annealing temperatures or grain size play important roles for the intensities of blue-green light emission, and the oxygen vacancies should be responsible for this emission. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:294 / 298
页数:5
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