Excess molar volumes of (an isomer of butanol plus benzene or toluene) at the temperature 308.15 K

被引:28
作者
Bhardwaj, U [1 ]
Maken, S [1 ]
Singh, KC [1 ]
机构
[1] MAHARSHI DAYANAND UNIV,DEPT CHEM,ROHTAK 124001,HARYANA,INDIA
关键词
D O I
10.1006/jcht.1996.0103
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar volumes of (butan-1-ol, or butan-2-ol, or 2-methylpropan-1-ol, or 2-methylpropan-2-ol + benzene, or toluene) over the entire range of composition have been measured dilatometrically at the temperature 308.15 K. The results indicate that the branching of an alkyl group of butanol near the hydroxyl group makes both the hydrogen bonding and the electron donor-acceptor interactions between butanol and benzene or toluene molecules less effective. (C) 1996 Academic Press Limited
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页码:1173 / 1177
页数:5
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