Complexes of adrenaline with some divalent transition-metal ions

被引：8
|
作者：
Materazzi, S [1 ]
Nugnes, C [1 ]
Gentili, A [1 ]
Curini, R [1 ]
机构：
[1] Univ Rome La Sapienza, Dept Chem, I-00185 Rome, Italy
来源：
THERMOCHIMICA ACTA | 2001年 / 369卷 / 1-2期
关键词：
adrenaline; complexes; TG-FTIR; EGA; epinephrine; decomposition;
D O I：
10.1016/S0040-6031(00)00753-X
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A thermoanalytical study of different adrenaline coordination compounds with some divalent transition-metal ions such as Co(II), Ni(II) and Cu(II) is reported. The solid precipitated compounds were characterized by elemental analysis and by thermogravimetric analysis also coupled to FTIR spectroscopy to analyze the evolved gases and make consistent the proposed decomposition steps. Several complexes were obtained with the metal/ligand molar ratios of 1:2, 1:4 and 1:6. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：167 / 173
页数：7
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