A new three-dimensional zinc(ii) metal-organic framework as a fluorescence sensor for sensing the biomarker 3-nitrotyrosine

被引：77

作者：

Geng, Jun ^{[1
]}

Li, Yuyao ^{[1
]}

Lin, Hongyan ^{[1
]}

Liu, Qianqian ^{[1
]}

Lu, Junjun ^{[1
]}

Wang, Xiuli ^{[1
]}

机构：

[1] Bohai Univ, Coll Chem & Mat Engn, Liaoning Profess Technol Innovat Ctr Liaoning Pro, Jinzhou 121013, Peoples R China

来源：

DALTON TRANSACTIONS | 2022年 / 51卷 / 30期

基金：

中国国家自然科学基金;

关键词：

SELECTIVE DETECTION; COORDINATION POLYMERS; SENSITIVE DETECTION; BIOLOGICAL SAMPLES; OXIDATIVE STRESS; NITRATION; IONS; DYES; QUANTIFICATION; IDENTIFICATION;

D O I：

10.1039/d2dt01800d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3-Nitrotyrosine (3-NT), an oxidative stress biomarker, is closely associated with various diseases. Thus, rapid and sensitive detection of 3-NT is of great significance for preventing and treating diseases. Herein, we reported a new 3D zinc-based metal-organic framework (Zn-MOF) [Zn(L)(HBTC)] (L = (E)-4,4 '-(ethene-1,2-diyl)bis[(N-pyridin-3-yl)benzamide], H3BTC = 1,3,5-benzenetricarboxylic acid), which was structurally characterized by single crystal X-ray diffraction, IR, PXRD and TG. The Zn-MOF can be used as a highly efficient fluorescence sensing material to provide a direct and low-cost method for the rapid detection of 3-NT and shows high sensitivity with a K-SV value of 6.596 x 10(4) M-1, a rapid luminescence response within 24 s, excellent selectivity, high anti-interference ability and good recyclability. It is the first example of a MOF being used to directly detect 3-NT as a luminescence sensor to our knowledge. The sensing mechanism of the Zn-MOF towards 3-NT is discussed in detail, which provides a basis for the rational design of MOF sensing materials and their application in biomarker detection.

引用

页码：11390 / 11396

页数：7

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