Structural, Morphological and Optical Properties of V2O5 Nanorods Grown Using Spray Pyrolysis Technique at Different Substrate Temperature

被引:0
|
作者
Abd-Alghafour, N. M. [1 ,2 ]
Ahmed, Naser. M. [2 ]
Hassan, Z. [2 ]
Mohammad, Sabah M. [2 ]
Bououdina, M. [3 ]
Ali, M. K. M. [4 ]
机构
[1] Iraqi Minist Educ, Al Anbar, Iraq
[2] Univ Sains Malaysia, Sch Phys, Nanooptoelect Res & Technol Lab, George Town 11800, Malaysia
[3] Univ Bahrain, Coll Sci, Dept Phys, POB 32038, Zallaq, Bahrain
[4] Al Imam Mohammad Ibn Saud Islamic Univ, Coll Sci, Phys Dept, Riyadh 11623, Saudi Arabia
关键词
V2O5; Spray Pyrolysis; Substrate Temperature; Nanorods; Optical Properties; THIN-FILMS; SENSOR ARRAY; OXIDE; TRANSPORT; MECHANISM;
D O I
10.1166/nnl.2016.2062
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
V2O5 NRs were prepared by a spray pyrolysis onto heated glass substrates at various substrate temperatures. X-ray diffraction (XRD) results indicated that the films obtained at T-s = 250 degrees C have low peak intensities. However, the degree of crystallinity increases when the temperature was increases to Ts = 350 degrees C, and films have orthorhombic structures with preferential orientations Ts = 350 degrees C. The optical band gap is determinedalong the (110) direction. FESEM observations showed that rod-like shaped morphology is in the 100-150 nm diameter range and in the 1-3 mu m length range. Optical transmittance in the visible range increases to reach a maximum value of approximately 80%, at a substrate temperature of T-s = 350 degrees C. The optical band gap is determined when there is a decline in optical absorbance spectra at an increasing substrate temperature 2.46 eV in the amorphous phase at 250 degrees C to 2.02 eV in the nanocrystalline phase at 350 degrees C. Photoluminescence spectra revealed two main broad peaks at around 516-533 nm with high intensity.
引用
收藏
页码:181 / 186
页数:6
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