10 Years of Click Chemistry: Synthesis and Applications of Ferrocene-Derived Triazoles

被引:122
作者
Ganesh, Venkataraman [1 ]
Sudhir, V. Sai [1 ]
Kundu, Taraknath [1 ]
Chandrasekaran, Srinivasan [1 ]
机构
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
关键词
click chemistry; copper; cycloaddition; ferrocene conjugates; triazoles; MOLECULAR RECOGNITION; BETA-CYCLODEXTRIN; METAL-COMPLEXES; 1,3-DIPOLAR CYCLOADDITION; CENTRAL CHIRALITY; ELECTRON-TRANSFER; AZOMETHINE YLIDE; PNA OLIGOMERS; DENDRIMERS; LIGANDS;
D O I
10.1002/asia.201100408
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Click chemistry has played a significant role as a rapid and versatile strategy for conjugating two molecular fragments under very mild reaction conditions. Introduction of ferrocene-derived triazole systems using click chemistry has attracted enormous interest in various fields due to its potential applications in electrochemical techniques for detection and sensing. The present discussion focuses on the synthesis of ferrocene-triazole and the importance of using a CuAAC reaction for such conjugation. Applications of ferrocene-based click reactions in conjugate chemistry, asymmetric catalysis, medicinal chemistry, host-guest interactions, and materials chemistry have been highlighted.
引用
收藏
页码:2670 / 2694
页数:25
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