In Situ Ring-Closing Strategy for Direct Synthesis of N-Heterocyclic Carbene Nickel Complexes and Their Application in Coupling of Allylic Alcohols with Aryl Boronic Acids

被引：23

作者：

Wang, Yu-Bin ^{[1
]}

Liu, Bin-Yuan ^{[2
]}

Bu, Qingqing ^{[1
]}

Dai, Bin ^{[1
]}

Liu, Ning ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China

[2] Hebei Univ Technol, Sch Chem Engn & Technol, Hebei Key Lab Funct Polymers, Tianjin 300130, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 14期

基金：

中国国家自然科学基金;

关键词：

nickel; N-heterocyclic carbene; allylic alcohol; catalyst synthesis; coupling reaction; PINCER COMPLEX; C-C; CATALYTIC-ACTIVITY; ARYLBORONIC ACIDS; METAL-COMPLEXES; PALLADIUM; NHC; EFFICIENT; ACTIVATION; VERSATILE;

D O I：

10.1002/adsc.202000186

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A in situ ring-closing strategy was developed for the synthesis of N-heterocyclic carbene nickel complexes. The process was carried out in air, and did not require solvent purification. The resulting nickel complexes were investigated as catalysts for the coupling of allylic alcohols with aryl boronic acids. A wide range of allylic substrates and aryl acids proved to be applicable to this catalytic system. Control experiments suggest that the Ni(0) may be the true active species in the coupling reactions.

引用

页码：2930 / 2940

页数：11

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