A headspace gas chromatographic method for the analysis of cyclohexanone and cyclohexanol in a system involving metalloporphyrins as catalyst

被引：0

作者：

Knupp, VF ^{[1
]}

Idemori, YM ^{[1
]}

Cardeal, ZL ^{[1
]}

机构：

[1] Univ Fed Minas Gerais, ICEx, Dept Chem, BR-31270901 Belo Horizonte, MG, Brazil

来源：

CHROMATOGRAPHIA | 2001年 / 53卷 / 9-10期

关键词：

gas chromatography; static headspace sampling; metalloporphyrin catalysts; cyclohexanone and cyclohexanol;

D O I：

10.1007/BF02491617

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This paper describes a Headspace gas chromatographic method for the assay of compounds in synthesis involving metalloporphyrins as catalysts for alkan oxidation. The method gives good resolution, repeatability detection limit and shows a linear response, which demonstrates the suitability of the method for real samples. This procedure allows the determination of the reaction products of catalytic process and it does not contaminate the GC system.

引用

页码：529 / 533

页数：5

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