The effects of trans-polyoctylene rubber on thermal analysis and fatigue properties of styrene butadiene rubber/recycled acrylonitrile butadiene rubber

被引:16
作者
Noriman, N. Z. [2 ]
Ismail, H. [1 ]
Rashid, A. A. [1 ]
机构
[1] Univ Sains Malaysia, Sch Mat & Mineral Resources Engn, Perai, Penang, Malaysia
[2] Univ Malaysia Perlis, Sch Mat Engn, Arau 02600, Perlis, Malaysia
关键词
Fatigue analysis; Differential scanning calorimetry (DSC); SBR; NBR blends; Thermogravimetric analysis (TGA); TOR; MECHANICAL-PROPERTIES; PHASE MORPHOLOGY; BLENDS; POLYOCTENYLENE; TOR;
D O I
10.1002/adv.20240
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The incorporation of trans-polyoctylene rubber (TOR) into the blends of styrene butadiene rubber/recycled acrylonitrile butadiene rubber (SBR/NBRr) was investigated. The thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), and fatigue life of SBR/NBRr blends with and without TOR were studied. Results showed that SBR/NBRr blends with TOR exhibited better thermal stability than SBR/NBRr blends without TOR. A DSC result showed that with incorporation of TOR into the SBR/NBRr blends, it alters the calorimetric profile particularly for SBR/NBRr/TOR (R05/TOR), which shows changes in the horizontal line from a high to low energy level along with a greater delta H value. The fatigue life of SBR/NBRr blends with the incorporation of TOR showed higher values than SBR/NBRr blends without TOR, particularly at 75/25, 65/35, and 50/50 blend ratios. The scanning electron microscopy images of SBR/NBRr blends with TOR illustrated that the failure surface became rougher with many tear lines compared to SBR/NBRr without TOR, indicating that a good interaction occurred between the NBRr and SBR matrix with the presence of TOR. (c) 2011 Wiley Periodicals, Inc. Adv Polym Techn 32: 100108, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/adv.20240
引用
收藏
页码:100 / 108
页数:9
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