Dye-sensitized solar cells based on axially ligated phosphorus-phthalocyanine dyes

被引:5
作者
Hayat, Azwar [1 ]
Shivashimpi, Gururaj M. [1 ]
Nishimura, Terumi [1 ]
Fujikawa, Naotaka [1 ]
Ogomi, Yuhei [1 ]
Yamaguchi, Yoshihiro [2 ]
Pandey, Shyam S. [1 ]
Ma, Tingli [1 ]
Hayase, Shuzi [1 ]
机构
[1] Kyushu Inst Technol, Grad Sch Life Sci & Syst Engn, Kitakyushu, Fukuoka 8080196, Japan
[2] Nippon Steel & Sumikin Chem Co Ltd, Kitakyushu, Fukuoka 8048503, Japan
关键词
HIGH-EFFICIENCY; TRIAZATETRABENZCORROLES; AGGREGATION; BAND;
D O I
10.7567/APEX.8.047001
中图分类号
O59 [应用物理学];
学科分类号
摘要
Dye-sensitized solar cells with axially anchored phosphorous-phthalocyanine dyes were fabricated for the first time. Although the phosphorus-phthalocyanine dyes do not have a conventional anchoring group (-COOH), these dyes could be absorbed on a TiO2 semiconductor surface. After the optimization of energy levels, a 24% incident photon-to-current efficiency (IPCE) was observed at 710 nm with an IPCE curve edge of 800 nm. The efficiency was 2.67%, which was higher than those of previously reported dye-sensitized solar cells with axially anchored phthalocyanine dyes (less than 1%). (C) 2015 The Japan Society of Applied Physics
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页数:4
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