Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex

被引：11

作者：

Rabe, GW ^{[1
]}

Mitzel, NW ^{[1
]}

机构：

[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

INORGANICA CHIMICA ACTA | 2001年 / 316卷 / 1-2期

关键词：

terphenyl complexes; phosphane complexes; gold complexes;

D O I：

10.1016/S0020-1693(01)00389-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and X-ray crystal structure determination of a novel metal-terphenyl derivative, namely DmpAuPPh(3) (1). is reported (Dmp = 2,6-dimesitylphenyl). Complex 1 is synthesized by the reaction of one equivalent of DmDLi with one equivalent of Ph3PAuCl in tetrahydrofuran at room temperature in 70% yield. The molecular structure of monomeric 1 features a two-coordinate gold atom with an essentially linear arrangement of the two ligands with an interligand angle of 174.21(8)degrees as well as a slightly tilted terphenyl moiety. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：132 / 134

页数：3

共 12 条

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