(2,2′-Bipyridyl-κ2N,N′)chlorido(DL-threoninato-κ2N,O1)copper(II) monohydrate

被引:1
作者
Tan, Yi-Han [2 ]
Teoh, Siang-Guan [2 ]
Rosli, Mohd Mustaqim [1 ]
Fun, Hoong-Kun [1 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
DNA-BINDING; 1,10-PHENANTHROLINE; COMPLEXES; LIGANDS;
D O I
10.1107/S1600536811002583
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cu(C4H8NO3)Cl(C10H8N2)]center dot H2O, the Cu-II atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O, O-H center dot center dot center dot Cl, C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions link the molecules into a three-dimensional network. A pi-pi interaction with a centroid-centroid distance of 3.461 (1) angstrom is also present.
引用
收藏
页码:M262 / U1638
页数:11
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