Solution Processable Organic Solar Cell Based on Bulk Heterojunction Utilizing Phthalocyanine Derivative

被引:104
作者
Hori, Tetsuro [1 ]
Miyake, Yasuo [1 ,2 ]
Yamasaki, Naoyuki [1 ]
Yoshida, Hiroyuki [1 ]
Fujii, Akihiko [1 ]
Shimizu, Yo [2 ]
Ozaki, Masanori [1 ]
机构
[1] Osaka Univ, Div Elect Elect & Informat Engn, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Natl Inst Adv Ind Sci & Technol, Synthet Nanofunct Mat Grp, Res Inst Ubiquitous Energy Devices, Kansai Ctr, Osaka 5638577, Japan
关键词
PHOTOVOLTAIC CELLS; CONDUCTING POLYMER; BUCKMINSTERFULLERENE; EFFICIENCIES; C-60;
D O I
10.1143/APEX.3.101602
中图分类号
O59 [应用物理学];
学科分类号
摘要
Organic thin-film solar cells based on a bulk heterojunction utilizing the phthalocyanine derivative 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH(2)) have been studied. C6PcH(2) is soluble in common organic solvents such as chloroform, and the blend uniform thin film with the fullerene derivative 1-(3-methoxy-carbonyl)-propyl-1-1-phenyl-(6,6)C61 (PCBM) could be fabricated by a spin-coating method. Solar cells with an indium-tin-oxide/polymer hole transport layer/C6PcH(2):PCBM/Al structure, the active layer of which was prepared by a wet process using a low-weighted molecular system, have demonstrated a high external quantum efficiency of more than 70% in the Q-band absorption region of C6PcH(2) and a high energy conversion efficiency of 3.1%. (C) 2010 The Japan Society of Applied Physics
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页数:3
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