Ensuring homology between 2D and 3D molecular crystals

被引：18
|
作者：
Dang, Hung [1 ]
Maris, Thierry
Yi, Ji-Hyun
Rosei, Federico
Nanci, Antonio
Wuest, James D.
机构：
[1] Univ Montreal, Fac Med Dent, Dept Chim, Montreal, PQ H3C 3J7, Canada
[2] Inst Natl Rech Sci Energie Varennes, Varennes, PQ J3X 1S2, Canada
来源：
LANGMUIR | 2007年 / 23卷 / 24期
关键词：
D O I：
10.1021/la702885y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Integrated studies using scanning tunneling microscopy and X-ray crystallography have established that 4,5,9,-10-tetrahydropyrene-2,7-dicarboxylic acid and pyrene-2,7-dicarboxylic acid crystallizine 2D and 3D with striking homology. Different behavior is shown by related biphenyls that lack the planarizing conformational constraints of the pyrenyl core and the directing effects of intermolecular hydrogen bonding. The results of these studies show that molecules specifically designed to engage in multiple strong directional interadsorbate interactions are promising tools for imposing particular nanopatterns on surfaces and for revealing subtle aspects of crystallization.
引用
收藏
页码：11980 / 11985
页数：6
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