Catalytic oxidation of organic compounds in aqueous media

被引：169
作者：
Duprez, D
Delanoe, F
Barbier-Jr, J
Isnard, P
Blanchard, G
机构：
[1] RHONE POULENC RECH, F-93308 AUBERVILLIERS, FRANCE
[2] RHONE POULENC INDUSTRIALISAT, F-69153 DECINES CHARPIEU, FRANCE
来源：
CATALYSIS TODAY | 1996年 / 29卷 / 1-4期
关键词：
wet air oxidation; total organic carbon removal;
D O I：
10.1016/0920-5861(95)00298-7
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Ru, Pt and Ph catalysts supported on titania, ceria or active carbon and a Mn/Ce composite oxide catalysts were prepared and their catalytic behavior in Wet Air Oxidation (20 bar O-2) of phenol and acetic acid were investigated. Phenol was found to be an easily oxidizable compound as 170 degrees C, while acetic acid was a very refractory molecule, even at 200 degrees C. Ru(5 wt.-%)/C is a very efficient catalyst for the WAO of acetic acid without any leaching of noble metal.
引用
收藏
页码：317 / 322
页数：6
相关论文
共 17 条
[1]   EXPERIMENTAL KINETICS AND MECHANISTIC MODELING OF THE OXIDATION OF SIMPLE MIXTURES IN NEAR-CRITICAL WATER [J].
BOOCK, LT ;
KLEIN, MT .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (11) :2554-2562
[2]   HETEROGENIZED HOMOGENEOUS CATALYST .7. COMPARISONS OF THERMAL-OXIDATION AND HETEROGENIZED HOMOGENEOUS CO-TYPE AND MN-TYPE RESIN CATALYZED OXIDATION OF PROPIONALDEHYDE [J].
CHEN, LC ;
CHOU, TC .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (11) :2523-2529
[3]  
Daga N.S., 1986, INDIAN CHEM ENG, V28, P22
[4]   MECHANISM OF THE OXIDATION OF AQUEOUS PHENOL WITH DISSOLVED-OXYGEN [J].
DEVLIN, HR ;
HARRIS, IJ .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1984, 23 (04) :387-392
[5]  
DJAFER M, 1994, P 1 INT RES S WAT TR, P44
[6]   WET OXIDATION OF NON-WATER-SOLUBLE POLYMERS [J].
DUBOIS, MA ;
HUARD, T ;
MASSIANI, C .
ENVIRONMENTAL TECHNOLOGY, 1993, 14 (02) :195-200
[7]  
FOUSSARD JN, 1994, P 1 INT RES S WAT TR, P41
[8]   WET OXIDATION CATALYZED BY RUTHENIUM SUPPORTED ON CERIUM(IV) OXIDES [J].
IMAMURA, S ;
FUKUDA, I ;
ISHIDA, S .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1988, 27 (04) :718-721
[9]   WET OXIDATION OF POLY(ETHYLENE GLYCOL) CATALYZED BY MANGANESE CERIUM COMPOSITE OXIDE [J].
IMAMURA, S ;
NAKAMURA, M ;
KAWABATA, N ;
YOSHIDA, J ;
ISHIDA, S .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1986, 25 (01) :34-37
[10]  
Imamura S., 1987, J JAPAN PETROL I, V30, P199
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