Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system

被引：39

作者：

Feuerstein, M ^{[1
]}

Laurenti, D ^{[1
]}

Doucet, H ^{[1
]}

Santelli, M ^{[1
]}

机构：

[1] Fac Sci St Jerome, Synth Organ Lab, CNRS, UMR 6009, F-13397 Marseille 20, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 01期

关键词：

D O I：

10.1039/b007860n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)-cyclopentane/[PdCl(C3H5)](2) system catalyses allylic amination in good yields with a very high substrate/catalyst ratio; a turnover number of 680 000 and a turnover frequency of 8125 h(-1) can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.

引用

页码：43 / 44

页数：2

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