Enhanced luminescence and degradation resistance in Tb modified Yttrium Borate core-nano silica shell phosphor under UV and VUV excitation

被引:13
作者
Chawla, Santa [1 ]
Ravishanker [1 ]
Khan, A. F. [1 ]
Yadav, Ashish [1 ]
Chander, H. [1 ]
Shanker, V. [1 ]
机构
[1] Natl Phys Lab, New Delhi 110012, India
关键词
Solid state reaction and capping; HRTEM; Photoluminescence properties; Time resolved decay; PLASMA DISPLAY PANEL; VACUUM-ULTRAVIOLET; EMISSION; GREEN;
D O I
10.1016/j.apsusc.2011.03.082
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Composition variation in optimized solid state reaction conditions has been done to achieve intense green emission in YTbxBO3 phosphor under UV and VUV (147nm resonant Xe*, 172nm Xe-2* excimer band) excitation. Inert interface layer created by fabricating a shell of silica nanoparticles over individual phosphor grain protected the phosphor surface from deterioration and oxidation of luminescent ion (Tb3+) thus completely arresting phosphor degradation. At optimum Tb content of 20 mol%, integrated photoluminescence intensity of developed YTbxBO3 phosphor is four times higher than commercial green YBT. With short decay time of 4 ms, YTbxBO3 core-nano silica shell green emitting phosphor has great application potential in PDP panel and phosphor coated Xe lamps. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:7167 / 7171
页数:5
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