Electrical and optical properties of ZnO thin films prepared by magnetron rf sputtering - influence of Al, Er and H

被引:28
作者
Dimova-Malinovska, D. [1 ]
Nichev, H. [1 ]
Angelov, O. [1 ]
Grigorov, V. [1 ]
Kamenova, A. [1 ]
机构
[1] Bulgarian Acad Sci, Cent Lab Solar Energy & New Energy Sources, BU-1784 Sofia, Bulgaria
关键词
zinc oxide; thin films; X-ray diffraction; optical band gap; urbach band tail;
D O I
10.1016/j.spmi.2007.04.025
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The influence of Al, Er and H in ZnO thin films (ZnO:Al, ZnO:Er and ZnO:H) deposited by magnetron sputtering at different substrate temperatures, T-s, on their optical, structural and electrical properties was investigated. X-ray diffraction (XRD) analyses show an improvement of the crystalline structure with increasing T-s. The optical band gap, E-opt, of the films, from transmission and reflection spectra, ranged from 3.27 to 3.41 eV. The Urbach band tail width was also calculated. Incorporation of Al and Er resulted in a reduced and an increased resistivity, rho, respectively, and an increase in the Urbach tail width in both cases. However, sputtering in an Al + H-2 gas mixture led to an increase in p and an improvement in the structural order of the films. A discussion of the influence of T-s and of Al, Er and H on the properties is presented. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:123 / 128
页数:6
相关论文
共 16 条