Novel iridium complexes as yellow phosphorescent emitters for single-layer yellow and white polymer light-emitting diodes

We have designed two novel yellow phosphorescent iridium complexes with triphenylamine- and fluorene-functionalized cyclometalating ligands that are capable of producing highly efficient yellow and white polymer light-emitting devices (PLEDs). Both yellow and white-light-emission devices are achieved with an identical single-emission-layer configuration of ITO/PEDOT: PSS/emission layer (EML)/CsF/Al. For the yellow phosphorescent PLEDs based on Y1, the best device performances with a peak luminous efficiency (LE) of 15.1 cd A(-1) and a peak external quantum efficiency (EQE) of 7.6% are achieved. More importantly, the two-emitting-component WPLEDs containing iridum(III) bis(2-(4,6-difluorophenyl)-pyridinato-N,C-2') picolinate (FIrpic) as blue and Y1 as yellow phosphors doped into a PVK: OXD-7 matrix at an appropriate ratio exhibited a maximum LE of 14.7 cd A(-1), a maximum EQE of 8.6%, a maximum luminance of 5586 cd m(-2) and Commission Internationale de L'Eclairage (CIE) coordinates of (0.33, 0.42) which are close to the standard for white light emission. Moreover, at a luminance for practical application of 1000 cd m(-2), a good forward viewing LE of 14.4 cd A(-1) is obtained with a very slight decrease.