High Efficiency Membranes Based on PTMSP and Hyper-Crosslinked Polystyrene for Toxic Volatile Compounds Removal from Wastewater

被引:7
作者
Golubev, Georgy [1 ]
Sokolov, Stepan [1 ]
Rokhmanka, Tatyana [1 ]
Makaev, Sergey [1 ]
Borisov, Ilya [1 ]
Khashirova, Svetlana [2 ]
Volkov, Alexey [1 ]
机构
[1] RAS, AV Topchiev Inst Petrochem Synth, 29 Leninsky Prospekt, Moscow 119991, Russia
[2] Kabardino Balkar State Univ, Dept Organ Chem & Macromol Cpds, 173 Chernyshevsky St, Nalchik 360004, Russia
基金
俄罗斯科学基金会;
关键词
aromatic hydrocarbons; benzene; toluene; o-xylene; BTX; removal; PTMSP; polystyrene; mixed matrix membranes; pervaporation; MIXED MATRIX MEMBRANES; AQUEOUS-SOLUTIONS; ORGANIC-COMPOUNDS; PERVAPORATION PERFORMANCE; HYPERCROSSLINKED POLYSTYRENE; NANOFIBROUS MEMBRANES; COPOLYMER MEMBRANES; TOLUENE; SEPARATION; BTX;
D O I
10.3390/polym14142944
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
For the first time, membranes based on poly(1-trimethylsilyl-1-propyne) (PTMSP) with 5-50 wt% loading of hyper-crosslinked polystyrene sorbent particles (HCPS) were obtained; the membranes were investigated for the problem of effective removal of volatile organic compounds from aqueous solutions using vacuum pervaporation. The industrial HCPS sorbent Purolite Macronet (TM) MN200 was chosen due to its high sorption capacity for organic solvents. It has been found that the membranes are asymmetric when HCPS content is higher than 30 wt%; scanning electron microscopy of the cross-sections the membranes demonstrate that they have a clearly defined thin layer, consisting mainly of PTMSP, and a thick porous layer, consisting mainly of HCPS. The transport and separation characteristics of PTMSP membranes with different HCPS loading were studied during the pervaporation separation of binary and multicomponent mixtures of water with benzene, toluene and xylene. It was shown that the addition of HCPS up to 30 wt% not only increases the permeate fluxes by 4-7 times, but at the same time leads to 1.5-2 fold increase in the separation factor. It was possible to obtain separation factors exceeding 1000 for all studied mixtures at high permeate fluxes (0.5-1 kg/m(2)center dot h) in pervaporation separation of binary solutions.
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页数:16
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