Ultrathin Single-Walled Carbon Nanotube Network Framed Graphene Hybrids

Graphene and single-walled carbon nanotubes (SWNTs) have shown superior potential in electronics and optoelectronics because of their excellent thermal, mechanical, electronic, and optical properties. Here, a simple method is developed to synthesize ultrathin SWNT-graphene films through chemical vapor deposition. These novel two-dimensional hybrids show enhanced mechanical strength that allows them to float on water without polymer supporting layers. Characterizations by Raman spectroscopy and transmission electron microscopy indicate that SWNTs can interlace as a concrete backbone for the subsequent growth of monolayer graphene. Optical and electrical transport measurements further show that SWNT-graphene hybrids inherit high optical transparency and superior electrical conductivity from monolayer graphene. We also explore the local optoelectronic properties of SWNT-graphene hybrids through spatially resolved photocurrent microscopy and find that the interactions between SWNTs and graphene can induce a strong photocurrent response in the areas where SWNTs link different graphene domains together. These fundamental studies may open a door for engineering optoelectronic properties of SWNT-graphene hybrids by controlling the morphologies of the SWNT frames.