Ionic nature of Ge(II)-centered dications: a germanium K-edge X-ray absorption near edge structures study

被引：19

作者：

Ward, Matthew J. ^{[1
]}

Rupar, Paul A. ^{[1
]}

Murphy, Michael W. ^{[1
]}

Yiu, Yun-Mui ^{[1
]}

Baines, Kim M. ^{[1
]}

Sham, T. K. ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 37期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CHEMISTRY; PROGRESS; CATIONS;

D O I：

10.1039/c0cc01925a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Measurement of the ionic nature of [Ge(cryptand[2.2.2])](2+) by XANES has provided direct experimental evidence that the germanium center is best described as a nearly-naked dication encased within an electron rich cryptand cage.

引用

页码：7016 / 7018

页数：3

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