H2S interaction with HKUST-1 and ZIF-8 MOFs: A multitechnique study

被引：104

作者：

Ethiraj, Jayashree ^{[1
,2
]}

Bonino, Francesca ^{[1
,2
]}

Lamberti, Carlo ^{[3
,4
]}

Bordiga, Silvia ^{[1
,2
]}

机构：

[1] Univ Turin, NIS & INSTM Reference Ctr, Dept Chem, I-10135 Turin, Italy

[2] Univ Turin, NIS & INSTM Reference Ctr, Dept Chem, I-10125 Turin, Italy

[3] Southern Fed Univ, Rostov Na Donu 344090, Russia

[4] Univ Turin, CrisDi Ctr Crystallog, Dept Chem, I-10125 Turin, Italy

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2015年 / 207卷

关键词：

Metal-organic frameworks; Hydrogen sulfide; IR spectroscopy; Raman spectroscopy; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; HYDROGEN-SULFIDE ADSORPTION; MOF/GRAPHITE OXIDE COMPOSITES; SPECTROSCOPY; TEMPERATURE; ADSORBENTS; CATALYST; REMOVAL; GASES;

D O I：

10.1016/j.micromeso.2014.12.034

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The interaction of H2S with FIKUST-1 and ZIF-8 MOFs has been studied by means of FT-IR, Raman, DRUV-Vis-NIR and PXRD techniques. At very low equilibrium pressure (below 5 mbar) a stepwise structural distortion is observed in both HKUST-1 and ZIF-8. At higher equilibrium pressures (20-60 mbar), PXRD technique, in particular, showed the structural destruction of HKUST-1 with formation of a covallite (CuS) phase and some structural distortion of ZIF-8. (C) 2015 Elsevier Inc. All rights reserved.

引用

页码：90 / 94

页数：5

共 36 条

[1] Growth process monitoring and crystalline quality assessment of CuInS(Se)2 based solar cells by Raman spectroscopy [J].

Alvarez-García, J ;

Rudigier, E ;

Rega, N ;

Barcones, B ;

Scheer, R ;

Pérez-Rodríguez, A ;

Romano-Rodríguez, A ;

Morante, JR .

THIN SOLID FILMS, 2003, 431 :122-125

[2]

Bonino F, 2013, RSC CATAL SER, P76, DOI 10.1039/9781849737586-00076

[3] Adsorption properties of HKUST-1 toward hydrogen and other small molecules monitored by IR [J].

Bordiga, S. ;

Regli, L. ;

Bonino, F. ;

Groppo, E. ;

Lamberti, C. ;

Xiao, B. ;

Wheatley, P. S. ;

Morris, R. E. ;

Zecchina, A. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (21) :2676-2685

[4] X-ray absorption spectroscopies: useful tools to understand metallorganic frameworks structure and reactivity [J].

Bordiga, Silvia ;

Bonino, Francesca ;

Lillerud, Karl Petter ;

Lamberti, Carlo .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (12) :4885-4927

[5]

Borfecchia E, 2013, RSC CATAL SER, P143, DOI 10.1039/9781849737586-00143

[6] Insights into Adsorption of NH3 on HKUST-1 Metal-Organic Framework: A Multitechnique Approach [J].

Borfecchia, Elisa ;

Maurelli, Sara ;

Gianolio, Diego ;

Groppo, Elena ;

Chiesa, Mario ;

Bonino, Francesca ;

Lamberti, Carlo .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (37) :19839-19850

[7] Fundamental Aspects of H2S Adsorption on CPO-27-Ni [J].

Chavan, Sachin ;

Bonino, Francesca ;

Valenzano, Loredana ;

Civalleri, Bartolomeo ;

Lamberti, Carlo ;

Acerbi, Nadia ;

Cavka, Jasmina H. ;

Leistner, Matthias ;

Bordiga, Silvia .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (30) :15615-15622

[8] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[9]

Devic T., 2009, [No title captured], Patent No. [WO2009130251-A2, 2009130251]

[10]

Devic T., 2011, [No title captured], Patent No. [JP2011520592-W, 2011520592]

← 1 2 3 4 →