Synthesis and Directed Self-Assembly of Patterned Anisometric Polymeric Particles

被引:95
|
作者
Zhang, Zhenkun [1 ]
Pfleiderer, Patrick [1 ]
Schofield, Andrew B. [2 ]
Clasen, Christian [1 ]
Vermant, Jan [1 ]
机构
[1] Katholieke Univ Leuven, Dept Chem Engn, Louvain, Belgium
[2] Univ Edinburgh, Dept Phys, Edinburgh EH8 9YL, Midlothian, Scotland
基金
英国工程与自然科学研究理事会;
关键词
ELLIPSOIDAL PARTICLES; HARD-SPHERE; JANUS; INTERFACE; NANOPARTICLES; FABRICATION; COLLOIDS; DESIGN; SHAPE;
D O I
10.1021/ja108099r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple and versatile method for making chemically patterned anisotropic colloidal particles is proposed and demonstrated for two different types of patterning. Using a combination of thermo/mechanical stretching followed by a wet chemical treatment of a sterically stabilized latex, both patchy ellipsoidal particles with sticky interactions near the tips as well as particles with tunable fluorescent patterns could be easily produced. The potential of such model colloidal particles is demonstrated, specifically for the case of directed self-assembly.
引用
收藏
页码:392 / 395
页数:4
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