A simple and versatile method for making chemically patterned anisotropic colloidal particles is proposed and demonstrated for two different types of patterning. Using a combination of thermo/mechanical stretching followed by a wet chemical treatment of a sterically stabilized latex, both patchy ellipsoidal particles with sticky interactions near the tips as well as particles with tunable fluorescent patterns could be easily produced. The potential of such model colloidal particles is demonstrated, specifically for the case of directed self-assembly.
机构:
Korea Polytech Univ, Dept Chem Engn & Biotechnol, Siheung Si 15073, Gyeonggi Do, South KoreaKorea Polytech Univ, Dept Chem Engn & Biotechnol, Siheung Si 15073, Gyeonggi Do, South Korea
机构:
Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Univ Chicago, Inst Mol Engn, Chicago, IL 60637 USAArgonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Ramirez-Hernandez, Abelardo
Suh, Hyo Seon
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Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Univ Chicago, Inst Mol Engn, Chicago, IL 60637 USAArgonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Suh, Hyo Seon
Nealey, Paul F.
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Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Univ Chicago, Inst Mol Engn, Chicago, IL 60637 USAArgonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Nealey, Paul F.
de Pablo, Juan J.
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Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
Univ Chicago, Inst Mol Engn, Chicago, IL 60637 USAArgonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA