Lanthanide ions as templates for the synthesis of new dinuclear octadentate Schiff base complexes of podate type

被引:4
|
作者
Patroniak-Krzyminiewska, V [1 ]
Radecka-Paryzek, W [1 ]
机构
[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland
关键词
lanthanides; podate complexes; Schiff base complexes;
D O I
10.1016/S0925-8388(98)00469-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The template reactions of 2,6-diacetylpyridine with 1,12-diamine-4,9-dioxadodecane in the presence of lanthanide ions produce octadentate macroacyclic complexes of pedate type with terminal acetylpyridyl groups and a N4O4 set of donor atoms as a result of [2+1] Schiff base condensation. The complexes were characterized by spectral data (IR, UV-vis, H-1-NMR, FAB-MS) and thermogravimetric and elemental analysis. (C) 1998 Published by Elsevier Science S.A.
引用
收藏
页码:822 / 826
页数:5
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