MoS2/N-doped graphene aerogles composite anode for high performance sodium/potassium ion batteries

被引:67
作者
Dong, Xiaoyu [1 ]
Xing, Zheng [1 ]
Zheng, Guojun [1 ]
Gao, Xinran [1 ]
Hong, Haiping [2 ]
Ju, Zhicheng [1 ,3 ]
Zhuang, Quanchao [1 ]
机构
[1] China Univ Min & Technol, Sch Mat & Phys, Jiangsu Prov Engn Lab High Efficient Energy Stora, Xuzhou 221116, Jiangsu, Peoples R China
[2] South Dakota Sch Mines & Technol, Dept Elect Engn, Rapid City, SD 57701 USA
[3] Chinese Acad Sci, Inst Coal Chem, CAS Key Lab Carbon Mat, Taiyuan 030001, Peoples R China
基金
中国国家自然科学基金;
关键词
Sodium-ion batteries; Potassium -ion batteries; MoS2/Nitrogen doping aerogel; Electrochemical performance; DOPED GRAPHENE; HIGH-CAPACITY; LITHIUM; CATHODE;
D O I
10.1016/j.electacta.2020.135932
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Three-dimensional porous MoS2/nitrogen-doped graphene aerogels (MoS2/NGA) with different MoS2 loading masses were synthesized by a simple hydrothermal method. The unique structure can provide more Na+ (K+) transport channels and the three-dimensional porous morphology could greatly absorb the volume expansion of MoS2 during charging and discharging process. As the anode of sodium-ion batteries (SIBs), this material provides a specific capacity of 673 mAh g(-1) at a current density of 100 mA g(-1) with long cycle stability. In addition, the composite shows a specific capacity of 305 mAh g(-1) at 2000 mA g(-1) and exhibits excellent capacity reversibility after rate performance test, indicating that it is a promising anode choice for SIB. As the anode material of potassium-ion batteries (KlBs), it provides a reversible specific capacity of 349 mAh g(-1 )at a current density of 100 mA g(-1). It has a specific capacity of 72 mAhg(-1) at 5000 mAg(-1) and exhibits excellent capacity reversibility after rate performance test as well. Therefore, this work provides some insights into the fabrication of MoS2/graphene composites and is helpful for the design of high-performance anode materials of metal ion batteries. (C) 2020 Elsevier Ltd. All rights reserved.
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页数:12
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