Efficient oxidative coupling of amines to imines catalyzed by manganese(III) meso-tetraphenylporphyrin chloride under ambient conditions

被引：46

作者：

Yuan, Qiu-Lan ^{[2
]}

Zhou, Xian-Tai ^{[1
]}

Ji, Hong-Bing ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Longyan Univ, Sch Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2010年 / 12卷 / 03期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Amines; Imines; Oxidative coupling; Metalloporphyrins; MOLECULAR-ORBITAL THEORY; AEROBIC OXIDATION; N-BENZYLBENZALDIMINES; BENZYLAMINES; ACID; ENAMINES; GOLD;

D O I：

10.1016/j.catcom.2010.09.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Highly efficient oxidative coupling of amines to amines by tert butyl hydroperoxide (t-BuOOH) in the presence of metalloporphyrins has been reported Manganese porphyrin showed excellent activity and selectivity for the oxidative coupling of amines to imines under ambient conditions Moreover a plausible mechanism involving high valence oxo intermediate has been proposed (C) 2010 Elsevier B V All rights reserved

引用

页码：202 / 206

页数：5

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