Electrophilic fluorodesilylation of allenylmethylsilanes: A novel entry to 2-fluoro-1,3-dienes

被引：44
作者：
Pacheco, MC [1 ]
Gouverneur, V [1 ]
机构：
[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 07期
关键词：
D O I：
10.1021/ol047319z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several substitution patterns, including di- and trisubstituted compounds.
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页码：1267 / 1270
页数：4
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