Palladium-catalyzed deracemization of allylic carbonates in water with formation of allylic alcohols:: Hydrogen carbonate ion as nucleophile in the palladium-catalyzed allylic substitution and kinetic resolution

被引：93
|
作者：
Lüssem, BJ [1 ]
Gais, HJ [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 20期
关键词：
D O I：
10.1021/ja034109t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：6066 / 6067
页数：2
相关论文
共 50 条
  • [21] Palladium-Catalyzed Allylic Alkylation via Photocatalytic Nucleophile Generation
    Shen, Yang
    Dai, Zhen-Yao
    Zhang, Cheng
    Wang, Pu-Sheng
    ACS CATALYSIS, 2021, 11 (12) : 6757 - 6762
  • [22] PALLADIUM-CATALYZED ARYLATION OF ALLYLIC ALCOHOLS WITH ARYL HALIDES
    MELPOLDER, JB
    HECK, RF
    JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (02): : 265 - 272
  • [23] Palladium-catalyzed reactions of indolic triflate with allylic alcohols
    Malapel-Andrieu, B
    Merour, JY
    TETRAHEDRON LETTERS, 1998, 39 (1-2) : 39 - 42
  • [24] Palladium-catalyzed allylic substitution reaction in polymer synthesis
    Nomura, N
    Tsurugi, K
    Yoshida, N
    Okada, M
    CURRENT ORGANIC SYNTHESIS, 2005, 2 (01) : 21 - 38
  • [25] Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazolide
    Liu, Wei
    Zhang, Dazhi
    Zheng, Shengcai
    Yue, Yinshuang
    Liu, Dongge
    Zhao, Xiaoming
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 2011 (31) : 6288 - 6293
  • [26] Asymmetric Synthesis of ,-Disubstituted Allylic Amines through Palladium-Catalyzed Allylic Substitution
    Guo, Wusheng
    Cai, Aijie
    Xie, Jianing
    Kleij, Arjan W.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (39) : 11797 - 11801
  • [27] Palladium-catalyzed substitution reaction of allylic derivatives with tinacetylene
    Nishikawa, T
    Isobe, M
    BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY, 1999, 63 (01) : 238 - 242
  • [28] Kinetic resolution of primary allylic amines via palladium-catalyzed asymmetric allylic alkylation of malononitriles
    Wang, Yong
    Xu, Ya-Nan
    Fang, Guo-Sheng
    Kang, Hong-Jian
    Gu, Yonghong
    Tian, Shi-Kai
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (19) : 5367 - 5371
  • [29] PALLADIUM-CATALYZED, ENANTIOSELECTIVE ALLYLIC SUBSTITUTIONS
    REISER, O
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (04): : 547 - 549
  • [30] Palladium-catalyzed enantioselective allylic phosphination
    Butti, Pietro
    Rochat, Raphael
    Sadow, Aaron D.
    Togni, Antonio
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (26) : 4878 - 4881
12345