Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters

被引：267
作者：
Coventry, DN
Batsanov, AS
Goeta, AE
Howard, JAK
Marder, TB
Perutz, RN
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 16期
关键词：
D O I：
10.1039/b501778e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The selectivity of the iridium boryl complex-catalysed reaction of pyrene and perylene with B-2(pin)(2) (pin = OCMe2CMe2O) has been employed in the synthesis of D-2h-symmetry pyrene-2,7-( Bpin)(2) and D-4h-symmetry perylene-2,5,8,11-(Bpin)(4) providing direct borylation of positions which are otherwise difficult to derivatise.
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页码：2172 / 2174
页数：3
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