Aqueous-Phase Aerobic Oxidation of Alcohols by Ru/C in the Presence of Cyclodextrin: One-Pot Biomimetic Approach to Quinoxaline Synthesis

被引：39

作者：

Akkilagunta, Vijay Kumar ^{[1
]}

Reddy, Vutukuri Prakash ^{[1
]}

Kakulapati, Rama Rao ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500607, Andhra Pradesh, India

来源：

SYNLETT | 2010年 / 17期

关键词：

alcohols; biomimetic synthesis; cyclodextrins; oxidation; Ru/C; BETA-CYCLODEXTRIN; CATALYZED OXIDATION; SUPRAMOLECULAR CATALYSIS; SELECTIVE OXIDATION; EFFICIENT OXIDATION; MOLECULAR-OXYGEN; ALDEHYDES; PALLADIUM; WATER; KETONES;

D O I：

10.1055/s-0030-1258775

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aerobic oxidation of alcohols and synthesis of quinoxalines was developed in a one-pot biomimetic approach using recyclable ruthenium on charcoal and randomly methylated beta-cyclodextrin in water under neutral conditions overcoming many of the drawbacks in the earlier methodologies. The catalytic system can be recycled up to five cycles without loss of activity.

引用

页码：2571 / 2574

页数：4

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