Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines

被引：129

作者：

Huang, Yinhua ^{[1
]}

Pullarkat, Sumod A. ^{[1
]}

Li, Yongxin ^{[1
]}

Leung, Pak-Hing ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 37期

关键词：

CATALYZED ACRYLONITRILE HYDROPHOSPHINATION; ENANTIOSELECTIVE SYNTHESIS; PROMOTED HYDROAMINATION; ACTIVATED OLEFINS; C BOND; P-C; 1,4-ADDITION; CHEMISTRY; INSERTION; ANILINE;

D O I：

10.1039/c0cc00925c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organo-palladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines.

引用

页码：6950 / 6952

页数：3

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