Molecularly imprinted adsorbents for preconcentration and isolation of progesterone and testosterone by solid phase extraction combined with HPLC

被引：25

作者：

Ricanyova, Julia ^{[1
,2
]}

Gadzala-Kopciuch, Renata ^{[1
]}

Reiffova, Katarina ^{[2
]}

Bazel, Yaroslav ^{[2
]}

Buszewski, Boguslaw ^{[1
]}

机构：

[1] Nicolaus Copernicus Univ, Fac Chem, Dept Environm Chem & Bioanalyt, PL-87100 Torun, Poland

[2] Safarik Univ, Inst Chem, Dept Analyt Chem, Kosice 04154, Slovakia

来源：

ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY | 2010年 / 16卷 / 4-5期

关键词：

Steroids; Molecularly imprinted adsorbents; MISPE; HPLC; DAD; PERFORMANCE LIQUID-CHROMATOGRAPHY; HUMAN URINE; STEROID-HORMONES; POLYMERS; ESTROGENS; VALIDATION; SEPARATION; ESTRADIOL; EXCRETION; MONOMERS;

D O I：

10.1007/s10450-010-9265-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of a novel procedure of solid-phase extraction with molecularly imprinted polymers (MISPE) has been described. A MISPE procedure relying on tailor-made, artificial-mimic materials capable of selectively rebinding target analytes (steroids) based on a combination of recognition mechanisms, such as size, shape and functionality, was custom designed for progesterone and testosterone. The combination of MISPE with LC/DAD is a simple and an efficient method for the determination and quality control of progesterone and testosterone in human urine samples.

引用

页码：473 / 483

页数：11

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