Catalytic activation of hydrogen, silicon, and fluorine by transition-metal complexes

被引：11

作者：

Rauf, Waqar ^{[1
]}

Hazari, Amaruka ^{[1
]}

Gouverneur, Veronique ^{[1
]}

Brown, John M. ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

PURE AND APPLIED CHEMISTRY | 2010年 / 82卷 / 07期

关键词：

allylic alkylation; C-H activation; fluoride; palladium; silyl transfer; ELECTROPHILIC FLUORINATION; ROOM-TEMPERATURE; SUBSTITUTION; OLEFINS; PALLADIUM(0); MECHANISM; ARYLATION; ALKENES; METHYL; ARYL;

D O I：

10.1351/PAC-CON-09-10-37

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The remarkable versatility of palladium catalysis is exemplified by recent work in two distinct areas. Firstly, coupling chemistry is discussed, in which the reactive entity is generated by cleavage of a C-H or C-Si bond. The second part concerns the activation of allylic C-F bonds, where divergence from the normal stereochemical pattern of the reaction was observed.

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页码：1415 / 1428

页数：14

相关论文

共 26 条

[1]

AGENET N, 2002, ARKIVOC 92

[2] Selective Pd-catalyzed oxidative coupling of anilides with olefins through C-H bond activation at room temperature [J].

Boele, MDK ;

van Strijdonck, GPF ;

de Vries, AHM ;

Kamer, PCJ ;

de Vries, JG ;

van Leeuwen, PWNM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (08) :1586-1587

[3] Chemistry with [18F]fluoride ion [J].

Cai, Lisheng ;

Lu, Shuiyu ;

Pike, Victor W. .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (17) :2853-2873

[4] Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles [J].

Capito, E ;

Brown, JM ;

Ricci, A .

CHEMICAL COMMUNICATIONS, 2005, (14) :1854-1856

[5] PALLADIUM-CATALYZED CROSS-COUPLING OF ARYL AND ALKENYL BORONIC ACIDS WITH ALKENES VIA OXIDATIVE ADDITION OF A CARBON-BORON BOND TO PALLADIUM(0) [J].

CHO, CS ;

UEMURA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 465 (1-2) :85-92

[6] AROMATIC SUBSTITUTION OF OLEFINS .6. ARYLATION OF OLEFINS WITH PALLADIUM(II) ACETATE [J].

FUJIWARA, Y ;

MORITANI, I ;

DANNO, S ;

ASANO, R ;

TERANISH.S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) :7166-&

[7] Analysis of the concerted metalation-deprotonation mechanism in palladium-catalyzed direct arylation across a broad range of aromatic substrates [J].

Gorelsky, Serge I. ;

Lapointe, David ;

Fagnou, Keith .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10848-+

[8] ISOMERIZATION OF (PI-ALLYL)PALLADIUM COMPLEXES VIA NUCLEOPHILIC DISPLACEMENT BY PALLADIUM(0) - A COMMON MECHANISM IN PALLADIUM(0)-CATALYZED ALLYLIC SUBSTITUTION [J].

GRANBERG, KL ;

BACKVALL, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (17) :6858-6863

[9] Palladium-Catalyzed Substitution of Allylic Fluorides [J].

Hazari, Amaruka ;

Gouverneur, Veronique ;

Brown, John M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (07) :1296-1299

[10] Sequential Introduction of Carbon Nucleophiles onto Silicon Atoms Using Methyl as a Leaving Group [J].

Horie, Hiroaki ;

Kajita, Yuichi ;

Matsubara, Seijiro .

CHEMISTRY LETTERS, 2009, 38 (02) :116-117